Synthesis of polystyrene with high melting temperature through BDE/CuCl catalyzed polymerization

No matter what the polymerization manner was, polystyrene withunique high Tm (Tm = 170-285℃) was obtained through polymerization of styrene if the amount of BDE/CuCl catalyst was highly increased (mol ratio: St:CuCl = 25:1-2.5:1). Partial crystallinity of the PSt was observed by characterizations of X-ray diffraction and DSC. Spectra of 1H-NMR and 13C-NMR showed that syndiotactic structure contained in the obtained PSt was 5% more than that in aPSt (atactic polystyrene). According to the proposed "coordinated radical cage" mechanism, the coordinated state between radical and catalyst center metal Cu should be more closely packed with increasing the BDE/CuCl catalyst amount, which was induced to partial stereospecific polymerization in the coordinated radical polymerization of St.

作 者： Wan Xiaolong NI Baibing Liu Yanfei YING Shengkang   作者單位： Lab of Living Polymerization, East China University of Science and Technology, Shanghai 200237, China  刊 名： 中國科學(xué)B輯(英文版)  EI SCI 英文刊名： SCIENCE IN CHINA(SCIENTIA SINICA)  年，卷(期)： 2001 44(1)  分類號： O6  關(guān)鍵詞： polystyrene   "living"/controlled polymerization   synthesis   bis(dimethylaminoethyl) ether  

【Synthesis of polystyrene with high m】相關(guān)文章：

Synthesis of 4-Aminosalicylglycine04-26

It is (high) time that05-04

Life of High Quality05-04

Study on synthesis of polylactide from kitchen garbage04-25

Synthesis of nanosize MnO2 and its performence04-27

Synthesis and Crystal Structure of Binuclear Copper(Ⅱ)Complex Containing (Dimethylaminomethyl)ferrocene04-27

《m f》教案02-23

學(xué)科術(shù)語 M05-04

單詞high的中文是什么意思02-12

4m×3m風(fēng)洞風(fēng)工程試驗段研制04-27